Multiple spintronic functionalities into single zinc-ferrous ferrite thin films

نویسندگان

چکیده

The ability to combine multiple spintronic properties in the ZnxFe3-xO4 system with different variants of its chemical composition offers a new and tantalizing route towards homodevices. This is mainly due advantage varying Zn component ZnxFe3-xO4, which leads possibility preserving spinel symmetry (within 5% lattice mismatch) while changing material from ferrimagnetic half-metal (x = 0) an insulating paramagnet 1). Here we demonstrate that thin films, grown ZnFe2O4 single phase target, laser-ablated under reduced atmosphere, exhibits reduction content, large 4πMS (6.5 kG), very low resistivity (25 mΩ cm) Verwey transition, all can be engineered by appropriate choice growth temperature. All these spectacular are confirmed ab initio calculations attributed inverse structure [Znx+2Fe1−x+3]A[Fe1+y+3Fe1−y+2]BO4-δ, where Fe+2 ions along Fe+3 occupy octahedral sites Zn+2 inverted sit tetrahedral sites. Phase formation laser ablated films compared bulk thermal equilibrium, shows there competition between O vacancies at various temperature zones.

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ژورنال

عنوان ژورنال: Journal of Alloys and Compounds

سال: 2022

ISSN: ['0925-8388', '1873-4669']

DOI: https://doi.org/10.1016/j.jallcom.2021.162425